Insights on hexagonal TbMnO3 for optoelectronic applications: From powders to thin films

نویسندگان

چکیده

In this work, we first report on the fabrication of TbMnO3 (TMO) powders and doping with In, Lu, Gd, Sm, Nd, Y. Nd atoms were found to significantly reduce cell size while preserving an orthorhombic structure. Conversely, show that hexagonal h-TMO, indium doped TMO (h-In-TMO), yttrium (h-Y-TMO), YMnO3 (h-YMO) can be obtained epitaxially using pulsed laser deposition (PLD) Pt (111)//Al2O3 (0001). The evolution optical properties was measured for PLD films a direct bandgap 1.5–1.6 eV h-TMO films. h-In-TMO h-Y-TMO showed no sign ferroelectricity at room temperature as opposed h-YMO. No short-circuit current in solar configuration under 1 sun illumination. However photovoltaic behavior observed by surface photovoltage h-YMO, indicating Y incorporation is helpful properties.

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ژورنال

عنوان ژورنال: Journal of Alloys and Compounds

سال: 2021

ISSN: ['0925-8388', '1873-4669']

DOI: https://doi.org/10.1016/j.jallcom.2021.160922